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Natural Cocoa Powder vs. Alkalized Cocoa Powder

Cocoa powder is a staple ingredient for many bakers and chocolate lovers. But did you know there are two types of cocoa powder: natural cocoa powder and alkalized cocoa powder (also known as Dutch processed)?


Understanding the difference between these two types can vastly impact the outcome of your recipe.


Natural cocoa powder is made from roasted cocoa beans that have had their fat (cocoa butter) removed. The remaining solids are ground into a fine powder with no other ingredients added. This type of cocoa powder is acidic, with a pH level between 5 and 6. Natural cocoa powder is often used in baking recipes that call for baking soda, as the acidity reacts with the baking soda to help baked goods rise.


On the other hand, alkalized cocoa powder is made from cocoa beans that have been treated with an alkalizing agent (usually potassium carbonate) to reduce the acidity. This process, also known as Dutch processing, results in a cocoa powder that is smoother, darker in color, and less bitter than natural cocoa powder. The pH level of alkalized cocoa powder is typically between 7 and 8.



The difference in acidity levels between natural and alkalized cocoa powder means that they cannot be used interchangeably in recipes. If a recipe calls for natural cocoa powder and you substitute it with alkalized cocoa powder, the end result will be a less acidic and less tangy flavor. Similarly, if you use natural cocoa powder in a recipe that calls for alkalized cocoa powder, the result will be a more acidic flavor and darker color. Most big chefs and bakers prefer alkalized cocoa powder for its milder flavor and smoother texture.


One common myth surrounding cocoa powder is that alkalized cocoa powder is less healthy than natural cocoa powder. While it is true that the alkalizing process can remove some of the flavanols (antioxidants) found in cocoa, the difference is relatively small. In fact, some studies have found that alkalized cocoa powder can have a higher antioxidant activity due to the change in pH level.

So, which type of cocoa powder should you use? It ultimately depends on your recipe and personal preference. If you’re making a recipe that calls for baking soda, stick with natural cocoa powder. If you want a smoother and less bitter chocolate flavor, go for alkalized cocoa powder. Remember, they cannot be used interchangeably, so be sure to follow the recipe instructions carefully.


Consequently, natural cocoa powder and alkalized cocoa powder may look similar, but they have distinct differences that can greatly impact the outcome of your recipe. Understanding these differences and knowing which one to use can help you achieve the perfect chocolate flavor in your baked goods.


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